Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate
Authors
Anđelković, KatarinaBogdanović, Goran
Jovanović, Dragoljub
Mitić, Dragana
Miodragović, Đenana
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In the reaction of ZnCl2 with tacrine hydrochloride in water novel tetracoordinated
(C13H15N2)2[ZnCl4].H2O complex has been obtained and characterized by elemental analysis,
molar conductivity and X-ray analysis. The structure contains two crystallographically different
molecules of protonated tacrine present as counter cations, [ZnCl4]2- complex anion and one
water solvent molecule. The counter cations slightly differ in puckering of the cyclohexenyl ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen
bonds. The π–π stacking interactions between the rings of protonated tacrine have been
evidenced in the crystal. The [ZnCl4]2- complex anion has distorted tetrahedral geometry. Three
out of four Cl atoms are involved in intermolecular hydrogen bonds. Intermolecular H-bond
interactions that involve Cl atoms affect the Zn-Cl bond lengths.
Source:
Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6-10, 2010, 2010, 83-83Publisher:
- Belgrade : Institute of Technical Sciences of SASA
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- Book of Abstract
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Fakultet veterinarske medicineTY - CONF AU - Anđelković, Katarina AU - Bogdanović, Goran AU - Jovanović, Dragoljub AU - Mitić, Dragana AU - Miodragović, Đenana PY - 2010 UR - https://vet-erinar.vet.bg.ac.rs/handle/123456789/2679 AB - In the reaction of ZnCl2 with tacrine hydrochloride in water novel tetracoordinated (C13H15N2)2[ZnCl4].H2O complex has been obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, [ZnCl4]2- complex anion and one water solvent molecule. The counter cations slightly differ in puckering of the cyclohexenyl ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. The π–π stacking interactions between the rings of protonated tacrine have been evidenced in the crystal. The [ZnCl4]2- complex anion has distorted tetrahedral geometry. Three out of four Cl atoms are involved in intermolecular hydrogen bonds. Intermolecular H-bond interactions that involve Cl atoms affect the Zn-Cl bond lengths. PB - Belgrade : Institute of Technical Sciences of SASA C3 - Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6-10, 2010 T1 - Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate SP - 83 EP - 83 UR - https://hdl.handle.net/21.15107/rcub_veterinar_2679 ER -
@conference{ author = "Anđelković, Katarina and Bogdanović, Goran and Jovanović, Dragoljub and Mitić, Dragana and Miodragović, Đenana", year = "2010", abstract = "In the reaction of ZnCl2 with tacrine hydrochloride in water novel tetracoordinated (C13H15N2)2[ZnCl4].H2O complex has been obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, [ZnCl4]2- complex anion and one water solvent molecule. The counter cations slightly differ in puckering of the cyclohexenyl ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. The π–π stacking interactions between the rings of protonated tacrine have been evidenced in the crystal. The [ZnCl4]2- complex anion has distorted tetrahedral geometry. Three out of four Cl atoms are involved in intermolecular hydrogen bonds. Intermolecular H-bond interactions that involve Cl atoms affect the Zn-Cl bond lengths.", publisher = "Belgrade : Institute of Technical Sciences of SASA", journal = "Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6-10, 2010", title = "Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate", pages = "83-83", url = "https://hdl.handle.net/21.15107/rcub_veterinar_2679" }
Anđelković, K., Bogdanović, G., Jovanović, D., Mitić, D.,& Miodragović, Đ.. (2010). Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate. in Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6-10, 2010 Belgrade : Institute of Technical Sciences of SASA., 83-83. https://hdl.handle.net/21.15107/rcub_veterinar_2679
Anđelković K, Bogdanović G, Jovanović D, Mitić D, Miodragović Đ. Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate. in Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6-10, 2010. 2010;:83-83. https://hdl.handle.net/21.15107/rcub_veterinar_2679 .
Anđelković, Katarina, Bogdanović, Goran, Jovanović, Dragoljub, Mitić, Dragana, Miodragović, Đenana, "Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate" in Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6-10, 2010 (2010):83-83, https://hdl.handle.net/21.15107/rcub_veterinar_2679 .