Electroanalytical determination of chloropromazine on boron-doped diamond electrode
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The electrochemical behavior and determination of chlorpromazine (CPZ)
by differential-pulse voltammetry (DPV) at unmodified boron-doped
diamond electrode (BDDE) is proposed. Effect of pH on electrochemical
oxidation of chloropromazine in Britton–Robinson (BR) buffer solution was
investigated. Cyclic voltammetry results shoved four oxidation peaks for
CPZ and peaks at 0.6 V and 1.3 V were chosen for CPZ quantification. The
electrode reaction is controlled by diffusion as a rate-determining step.
Under optimized DPV conditions at pH 4.0, a linear analytical curve was
obtained for wide the cloropomazine concentration range from 1.0×10-7
to
4.0×10-5M with a detection limit of 0.3×10-7M.
Source:
13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, September 26 - 30, 2016, 2016, 379-382Publisher:
- Belgrade : Society of Physical Chemists of Serbia
Funding / projects:
- Multiscale structuring of polymer nanocomposites and functional materials based on different precursors (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45022)
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Fakultet veterinarske medicineTY - CONF AU - Petković, Branka AU - Stanković, Dalibor AU - Kuzmanović, Darko AU - Dimitrijević, Teodora AU - Krstić, Milena PY - 2016 UR - https://vet-erinar.vet.bg.ac.rs/handle/123456789/3801 AB - The electrochemical behavior and determination of chlorpromazine (CPZ) by differential-pulse voltammetry (DPV) at unmodified boron-doped diamond electrode (BDDE) is proposed. Effect of pH on electrochemical oxidation of chloropromazine in Britton–Robinson (BR) buffer solution was investigated. Cyclic voltammetry results shoved four oxidation peaks for CPZ and peaks at 0.6 V and 1.3 V were chosen for CPZ quantification. The electrode reaction is controlled by diffusion as a rate-determining step. Under optimized DPV conditions at pH 4.0, a linear analytical curve was obtained for wide the cloropomazine concentration range from 1.0×10-7 to 4.0×10-5M with a detection limit of 0.3×10-7M. PB - Belgrade : Society of Physical Chemists of Serbia C3 - 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, September 26 - 30, 2016 T1 - Electroanalytical determination of chloropromazine on boron-doped diamond electrode SP - 379 EP - 382 UR - https://hdl.handle.net/21.15107/rcub_veterinar_3801 ER -
@conference{ author = "Petković, Branka and Stanković, Dalibor and Kuzmanović, Darko and Dimitrijević, Teodora and Krstić, Milena", year = "2016", abstract = "The electrochemical behavior and determination of chlorpromazine (CPZ) by differential-pulse voltammetry (DPV) at unmodified boron-doped diamond electrode (BDDE) is proposed. Effect of pH on electrochemical oxidation of chloropromazine in Britton–Robinson (BR) buffer solution was investigated. Cyclic voltammetry results shoved four oxidation peaks for CPZ and peaks at 0.6 V and 1.3 V were chosen for CPZ quantification. The electrode reaction is controlled by diffusion as a rate-determining step. Under optimized DPV conditions at pH 4.0, a linear analytical curve was obtained for wide the cloropomazine concentration range from 1.0×10-7 to 4.0×10-5M with a detection limit of 0.3×10-7M.", publisher = "Belgrade : Society of Physical Chemists of Serbia", journal = "13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, September 26 - 30, 2016", title = "Electroanalytical determination of chloropromazine on boron-doped diamond electrode", pages = "379-382", url = "https://hdl.handle.net/21.15107/rcub_veterinar_3801" }
Petković, B., Stanković, D., Kuzmanović, D., Dimitrijević, T.,& Krstić, M.. (2016). Electroanalytical determination of chloropromazine on boron-doped diamond electrode. in 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, September 26 - 30, 2016 Belgrade : Society of Physical Chemists of Serbia., 379-382. https://hdl.handle.net/21.15107/rcub_veterinar_3801
Petković B, Stanković D, Kuzmanović D, Dimitrijević T, Krstić M. Electroanalytical determination of chloropromazine on boron-doped diamond electrode. in 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, September 26 - 30, 2016. 2016;:379-382. https://hdl.handle.net/21.15107/rcub_veterinar_3801 .
Petković, Branka, Stanković, Dalibor, Kuzmanović, Darko, Dimitrijević, Teodora, Krstić, Milena, "Electroanalytical determination of chloropromazine on boron-doped diamond electrode" in 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, September 26 - 30, 2016 (2016):379-382, https://hdl.handle.net/21.15107/rcub_veterinar_3801 .