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Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines
dc.creator | Hollo, Berta | |
dc.creator | Krstić, Milena | |
dc.creator | Sovilj, Sofija P. | |
dc.creator | Meszaros-Szecsenyi, Katalin | |
dc.date.accessioned | 2020-06-03T13:43:54Z | |
dc.date.available | 2020-06-03T13:43:54Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1388-6150 | |
dc.identifier.uri | https://vet-erinar.vet.bg.ac.rs/handle/123456789/1034 | |
dc.description.abstract | The thermal decomposition of [RuCl2(eta(6)-p-cymene)](2) (1) and its biologically active N-alkylphenothiazine compounds of composition L[RuCl3(eta(6)-p-cymene)] where L = CPH+ (2), TFH+center dot HCl (3), and TRH+ (4) (chlorpromazine hydrochloride, CP center dot HCl; trifluoperazine dihydrochloride, TF center dot 2HCl; and thioridazine hydrochloride, TR center dot HCl, respectively) has been studied. The crystal and molecular structure of compound 3 was determined earlier by single crystal X-ray diffraction analysis. The thermal data were collected by simultaneous TG/DSC measurements. For evolved gas detection, the qualitative reaction of chlorides with AgNO3 in an acidic solution was applied. The measurements were carried out in the temperature range to 700 A degrees C in nitrogen atmosphere. Compounds of L[RuCl3(eta(6)-p-cymene)] crystallize with water or water/2-propanole. On the basis of thermal data, the trend in the solvent bonding energies was assessed. | en |
dc.publisher | Springer, Dordrecht | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS// | |
dc.relation | Secretariat for Science and Technological Development, Autonomous Province of Vojvodina, Republic of Serbia [114-451-02011/2007-02] | |
dc.relation | CEEPUS II program [CII-CZ-0212-04-1011] | |
dc.rights | restrictedAccess | |
dc.source | Journal of Thermal Analysis and Calorimetry | |
dc.subject | Ruthenium(II) complexes | en |
dc.subject | N-alkylphenothiazines | en |
dc.subject | Thermal decomposition | en |
dc.subject | EGD | en |
dc.title | Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Совиљ, Софија П.; Месзарос-Сзецсенyи, Каталин; Холло, Берта; Крстић, Милена; | |
dc.citation.volume | 111 | |
dc.citation.issue | 3 | |
dc.citation.spage | 1927 | |
dc.citation.epage | 1932 | |
dc.citation.other | 111(3): 1927-1932 | |
dc.citation.rank | M22 | |
dc.identifier.wos | 000315298800035 | |
dc.identifier.doi | 10.1007/s10973-011-1969-8 | |
dc.identifier.scopus | 2-s2.0-84881477742 | |
dc.type.version | publishedVersion |