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dc.creatorKrstić, Milena
dc.creatorPetković, Branka B.
dc.creatorMilcić, Milos
dc.creatorMišić, Dušan
dc.creatorFrancisco Santibanez, Juan
dc.date.accessioned2020-06-03T14:34:26Z
dc.date.available2020-06-03T14:34:26Z
dc.date.issued2019
dc.identifier.issn1857-5552
dc.identifier.urihttp://vet-erinar.vet.bg.ac.rs/handle/123456789/1752
dc.description.abstractTwo new nitrato complexes of zinc and nickel with 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc), have been synthesized and characterized. The IR spectral peaks showed that the coordinated and ionic nitrate ions are in agreement with the formula proposed by elemental analysis. Conductometric titrations predicted methanol to be a convenient solvent for synthesis and revealed the stoichiometry of the complexes, while molar electrical conductivities indicated a 1 : 3 complex electrolyte type for the zinc complex, and a 1 : 2 complex electrolyte type for the nickel complex. The optimized complex structure was obtained by molecular modeling and density functional theory calculations. The biological activity of the novel complexes was examined by screening eight different bacterial strains and two cancer cell lines. The zinc complex showed better antimicrobial activity against the bacterial strains, while the complexes did not show significance antiproliferative activity toward cancer cells MCF-7 and MDA-MB-231.en
dc.publisherSoc Chemists Technologists Madeconia, Skopje
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45022/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/175053/RS//
dc.rightsopenAccess
dc.sourceMacedonian Journal of Chemistry and Chemical Engineering
dc.subjectzincen
dc.subjectnickelen
dc.subjecttpmcen
dc.subjectcomplexen
dc.subjectbiological activityen
dc.titleSynthesis, characterization and biological study of new dinuclear zinc(ii) and nickel(ii) octaaza macrocyclic complexesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractКрстић, Милена; Петковић, Бранка Б.; Милцић, Милос; Францисцо Сантибанез, Јуан; Мишић, Душан;
dc.citation.volume38
dc.citation.issue1
dc.citation.spage1
dc.citation.epage11
dc.citation.other38(1): 1-11
dc.citation.rankM23
dc.identifier.wos000477950400002
dc.identifier.doi10.20450/mjcce.2019.1599
dc.identifier.scopus2-s2.0-85070517101
dc.identifier.fulltexthttp://veterinar.vet.bg.ac.rs/bitstream/id/714/1751.pdf
dc.identifier.rcubconv_2497
dc.type.versionpublishedVersion


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