Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate
Аутори
Anđelković, KatarinaFilipović, Nenad
Todorović, Tamara
Jovanović, Dragoljub
Tufegdžić, Srđan
Sladić, Dušan
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In search for agents that might show less negative side effects and overcome the
resistance to cisplatin, in this work a series of complexes of Cd(II), Cu(II), Pd(II) and Pt(II) with
the condensation product of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate were
synthesized. All four complexes were obtained by template synthesis. Elemental analysis, molar
conductivity, magnetic susceptibility (with Cu(II) complex), IR, 1
H NMR and 13C NMR spectral
data showed that all the obtained complexes had a coordination number four. In the neutral
square planar Pt(II), Pd(II) and Cd(II) complexes, the organic ligand is coordinated as a
bidentate via pyridine and hydrazone nitrogen atoms, the remaining two coordination sites being
occupied by chloride ion. In Cu(II) complex the ligand is coordinated as a tridentat, with
chloride in the fourth coordination site, so that the geometry is tetrahedral, and the complex is 1
: 1 electrolyte.
Извор:
Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007, 2007, 167-167Издавач:
- Belgrade : Institute of Technical Sciences of SASA
Напомена:
- Book of Abstract
Колекције
Институција/група
Fakultet veterinarske medicineTY - CONF AU - Anđelković, Katarina AU - Filipović, Nenad AU - Todorović, Tamara AU - Jovanović, Dragoljub AU - Tufegdžić, Srđan AU - Sladić, Dušan PY - 2007 UR - https://vet-erinar.vet.bg.ac.rs/handle/123456789/2680 AB - In search for agents that might show less negative side effects and overcome the resistance to cisplatin, in this work a series of complexes of Cd(II), Cu(II), Pd(II) and Pt(II) with the condensation product of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate were synthesized. All four complexes were obtained by template synthesis. Elemental analysis, molar conductivity, magnetic susceptibility (with Cu(II) complex), IR, 1 H NMR and 13C NMR spectral data showed that all the obtained complexes had a coordination number four. In the neutral square planar Pt(II), Pd(II) and Cd(II) complexes, the organic ligand is coordinated as a bidentate via pyridine and hydrazone nitrogen atoms, the remaining two coordination sites being occupied by chloride ion. In Cu(II) complex the ligand is coordinated as a tridentat, with chloride in the fourth coordination site, so that the geometry is tetrahedral, and the complex is 1 : 1 electrolyte. PB - Belgrade : Institute of Technical Sciences of SASA C3 - Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007 T1 - Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate SP - 167 EP - 167 UR - https://hdl.handle.net/21.15107/rcub_veterinar_2680 ER -
@conference{ author = "Anđelković, Katarina and Filipović, Nenad and Todorović, Tamara and Jovanović, Dragoljub and Tufegdžić, Srđan and Sladić, Dušan", year = "2007", abstract = "In search for agents that might show less negative side effects and overcome the resistance to cisplatin, in this work a series of complexes of Cd(II), Cu(II), Pd(II) and Pt(II) with the condensation product of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate were synthesized. All four complexes were obtained by template synthesis. Elemental analysis, molar conductivity, magnetic susceptibility (with Cu(II) complex), IR, 1 H NMR and 13C NMR spectral data showed that all the obtained complexes had a coordination number four. In the neutral square planar Pt(II), Pd(II) and Cd(II) complexes, the organic ligand is coordinated as a bidentate via pyridine and hydrazone nitrogen atoms, the remaining two coordination sites being occupied by chloride ion. In Cu(II) complex the ligand is coordinated as a tridentat, with chloride in the fourth coordination site, so that the geometry is tetrahedral, and the complex is 1 : 1 electrolyte.", publisher = "Belgrade : Institute of Technical Sciences of SASA", journal = "Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007", title = "Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate", pages = "167-167", url = "https://hdl.handle.net/21.15107/rcub_veterinar_2680" }
Anđelković, K., Filipović, N., Todorović, T., Jovanović, D., Tufegdžić, S.,& Sladić, D.. (2007). Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate. in Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007 Belgrade : Institute of Technical Sciences of SASA., 167-167. https://hdl.handle.net/21.15107/rcub_veterinar_2680
Anđelković K, Filipović N, Todorović T, Jovanović D, Tufegdžić S, Sladić D. Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate. in Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007. 2007;:167-167. https://hdl.handle.net/21.15107/rcub_veterinar_2680 .
Anđelković, Katarina, Filipović, Nenad, Todorović, Tamara, Jovanović, Dragoljub, Tufegdžić, Srđan, Sladić, Dušan, "Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate" in Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007 (2007):167-167, https://hdl.handle.net/21.15107/rcub_veterinar_2680 .