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Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate
dc.creator | Anđelković, Katarina | |
dc.creator | Filipović, Nenad | |
dc.creator | Todorović, Tamara | |
dc.creator | Jovanović, Dragoljub | |
dc.creator | Tufegdžić, Srđan | |
dc.creator | Sladić, Dušan | |
dc.date.accessioned | 2023-03-14T10:59:21Z | |
dc.date.available | 2023-03-14T10:59:21Z | |
dc.date.issued | 2007 | |
dc.identifier.isbn | 978-86-80321-11-0 | |
dc.identifier.uri | https://vet-erinar.vet.bg.ac.rs/handle/123456789/2680 | |
dc.description.abstract | In search for agents that might show less negative side effects and overcome the resistance to cisplatin, in this work a series of complexes of Cd(II), Cu(II), Pd(II) and Pt(II) with the condensation product of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate were synthesized. All four complexes were obtained by template synthesis. Elemental analysis, molar conductivity, magnetic susceptibility (with Cu(II) complex), IR, 1 H NMR and 13C NMR spectral data showed that all the obtained complexes had a coordination number four. In the neutral square planar Pt(II), Pd(II) and Cd(II) complexes, the organic ligand is coordinated as a bidentate via pyridine and hydrazone nitrogen atoms, the remaining two coordination sites being occupied by chloride ion. In Cu(II) complex the ligand is coordinated as a tridentat, with chloride in the fourth coordination site, so that the geometry is tetrahedral, and the complex is 1 : 1 electrolyte. | |
dc.language.iso | en | sr |
dc.publisher | Belgrade : Institute of Technical Sciences of SASA | sr |
dc.rights | openAccess | sr |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Ninth Annual Conference of the Yugoslav Materials Research Society YUCOMAT 2007, Herceg Novi, September 10-14, 2007 | sr |
dc.title | Synthesis and characterization of Cu(II), Cd(II), Pt(II), and Pd(II) complexes with condensation derivate of pyridine-2-carboxaldehyde and ethyl hydrazinoacetate | sr |
dc.type | conferenceObject | sr |
dc.rights.license | BY-NC-ND | sr |
dc.citation.spage | 167 | |
dc.citation.epage | 167 | |
dc.description.other | Book of Abstract | sr |
dc.identifier.fulltext | http://veterinar.vet.bg.ac.rs/bitstream/id/7802/bitstream_7802.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_veterinar_2680 | |
dc.type.version | publishedVersion | sr |