Further guaianolides from Amphoricarpos neumayeri ssp murbeckii from Montenegro
2006
Authors
Đorđević, IrisJadranin, Milka
Vajs, Vlatka
Menković, Nebojša
Tešević, Vele
Macura, Slobodan
Milosavljević, Slobodan M.
Article (Published version)
Metadata
Show full item recordAbstract
The aerial parts of Amphoricarpos neumayeri ssp. murbeckii afforded eleven guaianolides with the same relative (1 alpha H,4 beta H,5 alpha H, 7 alpha H) configuration of the basic skeleton. All of them contained a CH2OX (X = H, acetyl or isovaleroyl) group in 4 alpha-position, typical for amphoricarpolides. Four compounds (1-4) were isolated before from the same species, originating from different localities. Guaianolides 5-11 are new compounds. Compounds 7 and 8 were epoxidized at the 10 alpha(14)-position. Instead of the Delta(11(13))-double bond, observed in all previously isolated guaianolides from the same species, the four lactones contained 11 alpha,13-diol (8-10) or 11 alpha-OH, 13-chloro (11) moieties respectively.
Keywords:
Amphoricarpos neumayeri ssp murbeckii / sesquiterpene laetones / guaianolidesSource:
Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences, 2006, 61, 11, 1437-1442Publisher:
- Walter De Gruyter Gmbh, Berlin
Funding / projects:
- Sekundarni metaboliti samoniklih, lekovitih biljaka: izolovanje, karakterizacija i biloška aktivnost (RS-MESTD-MPN2006-2010-142053)
DOI: 10.1515/znb-2006-1119
ISSN: 0932-0776
WoS: 000243369900019
Scopus: 2-s2.0-33845648057
Collections
Institution/Community
Fakultet veterinarske medicineTY - JOUR AU - Đorđević, Iris AU - Jadranin, Milka AU - Vajs, Vlatka AU - Menković, Nebojša AU - Tešević, Vele AU - Macura, Slobodan AU - Milosavljević, Slobodan M. PY - 2006 UR - https://vet-erinar.vet.bg.ac.rs/handle/123456789/436 AB - The aerial parts of Amphoricarpos neumayeri ssp. murbeckii afforded eleven guaianolides with the same relative (1 alpha H,4 beta H,5 alpha H, 7 alpha H) configuration of the basic skeleton. All of them contained a CH2OX (X = H, acetyl or isovaleroyl) group in 4 alpha-position, typical for amphoricarpolides. Four compounds (1-4) were isolated before from the same species, originating from different localities. Guaianolides 5-11 are new compounds. Compounds 7 and 8 were epoxidized at the 10 alpha(14)-position. Instead of the Delta(11(13))-double bond, observed in all previously isolated guaianolides from the same species, the four lactones contained 11 alpha,13-diol (8-10) or 11 alpha-OH, 13-chloro (11) moieties respectively. PB - Walter De Gruyter Gmbh, Berlin T2 - Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences T1 - Further guaianolides from Amphoricarpos neumayeri ssp murbeckii from Montenegro VL - 61 IS - 11 SP - 1437 EP - 1442 DO - 10.1515/znb-2006-1119 ER -
@article{ author = "Đorđević, Iris and Jadranin, Milka and Vajs, Vlatka and Menković, Nebojša and Tešević, Vele and Macura, Slobodan and Milosavljević, Slobodan M.", year = "2006", abstract = "The aerial parts of Amphoricarpos neumayeri ssp. murbeckii afforded eleven guaianolides with the same relative (1 alpha H,4 beta H,5 alpha H, 7 alpha H) configuration of the basic skeleton. All of them contained a CH2OX (X = H, acetyl or isovaleroyl) group in 4 alpha-position, typical for amphoricarpolides. Four compounds (1-4) were isolated before from the same species, originating from different localities. Guaianolides 5-11 are new compounds. Compounds 7 and 8 were epoxidized at the 10 alpha(14)-position. Instead of the Delta(11(13))-double bond, observed in all previously isolated guaianolides from the same species, the four lactones contained 11 alpha,13-diol (8-10) or 11 alpha-OH, 13-chloro (11) moieties respectively.", publisher = "Walter De Gruyter Gmbh, Berlin", journal = "Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences", title = "Further guaianolides from Amphoricarpos neumayeri ssp murbeckii from Montenegro", volume = "61", number = "11", pages = "1437-1442", doi = "10.1515/znb-2006-1119" }
Đorđević, I., Jadranin, M., Vajs, V., Menković, N., Tešević, V., Macura, S.,& Milosavljević, S. M.. (2006). Further guaianolides from Amphoricarpos neumayeri ssp murbeckii from Montenegro. in Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences Walter De Gruyter Gmbh, Berlin., 61(11), 1437-1442. https://doi.org/10.1515/znb-2006-1119
Đorđević I, Jadranin M, Vajs V, Menković N, Tešević V, Macura S, Milosavljević SM. Further guaianolides from Amphoricarpos neumayeri ssp murbeckii from Montenegro. in Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences. 2006;61(11):1437-1442. doi:10.1515/znb-2006-1119 .
Đorđević, Iris, Jadranin, Milka, Vajs, Vlatka, Menković, Nebojša, Tešević, Vele, Macura, Slobodan, Milosavljević, Slobodan M., "Further guaianolides from Amphoricarpos neumayeri ssp murbeckii from Montenegro" in Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences, 61, no. 11 (2006):1437-1442, https://doi.org/10.1515/znb-2006-1119 . .