Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines
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2013
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The thermal decomposition of [RuCl2(eta(6)-p-cymene)](2) (1) and its biologically active N-alkylphenothiazine compounds of composition L[RuCl3(eta(6)-p-cymene)] where L = CPH+ (2), TFH+center dot HCl (3), and TRH+ (4) (chlorpromazine hydrochloride, CP center dot HCl; trifluoperazine dihydrochloride, TF center dot 2HCl; and thioridazine hydrochloride, TR center dot HCl, respectively) has been studied. The crystal and molecular structure of compound 3 was determined earlier by single crystal X-ray diffraction analysis. The thermal data were collected by simultaneous TG/DSC measurements. For evolved gas detection, the qualitative reaction of chlorides with AgNO3 in an acidic solution was applied. The measurements were carried out in the temperature range to 700 A degrees C in nitrogen atmosphere. Compounds of L[RuCl3(eta(6)-p-cymene)] crystallize with water or water/2-propanole. On the basis of thermal data, the trend in the solvent bonding energies was assessed.
Ključne reči:
Ruthenium(II) complexes / N-alkylphenothiazines / Thermal decomposition / EGDIzvor:
Journal of Thermal Analysis and Calorimetry, 2013, 111, 3, 1927-1932Izdavač:
- Springer, Dordrecht
Finansiranje / projekti:
- Dizajniranje, sinteza, karakterizacija i procena praktične primene koordinacionih i organometalnih jedinjenja (RS-MESTD-Basic Research (BR or ON)-172014)
- Secretariat for Science and Technological Development, Autonomous Province of Vojvodina, Republic of Serbia [114-451-02011/2007-02]
- CEEPUS II program [CII-CZ-0212-04-1011]
DOI: 10.1007/s10973-011-1969-8
ISSN: 1388-6150
WoS: 000315298800035
Scopus: 2-s2.0-84881477742
Kolekcije
Institucija/grupa
Fakultet veterinarske medicineTY - JOUR AU - Hollo, Berta AU - Krstić, Milena AU - Sovilj, Sofija P. AU - Meszaros-Szecsenyi, Katalin PY - 2013 UR - https://vet-erinar.vet.bg.ac.rs/handle/123456789/1034 AB - The thermal decomposition of [RuCl2(eta(6)-p-cymene)](2) (1) and its biologically active N-alkylphenothiazine compounds of composition L[RuCl3(eta(6)-p-cymene)] where L = CPH+ (2), TFH+center dot HCl (3), and TRH+ (4) (chlorpromazine hydrochloride, CP center dot HCl; trifluoperazine dihydrochloride, TF center dot 2HCl; and thioridazine hydrochloride, TR center dot HCl, respectively) has been studied. The crystal and molecular structure of compound 3 was determined earlier by single crystal X-ray diffraction analysis. The thermal data were collected by simultaneous TG/DSC measurements. For evolved gas detection, the qualitative reaction of chlorides with AgNO3 in an acidic solution was applied. The measurements were carried out in the temperature range to 700 A degrees C in nitrogen atmosphere. Compounds of L[RuCl3(eta(6)-p-cymene)] crystallize with water or water/2-propanole. On the basis of thermal data, the trend in the solvent bonding energies was assessed. PB - Springer, Dordrecht T2 - Journal of Thermal Analysis and Calorimetry T1 - Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines VL - 111 IS - 3 SP - 1927 EP - 1932 DO - 10.1007/s10973-011-1969-8 ER -
@article{ author = "Hollo, Berta and Krstić, Milena and Sovilj, Sofija P. and Meszaros-Szecsenyi, Katalin", year = "2013", abstract = "The thermal decomposition of [RuCl2(eta(6)-p-cymene)](2) (1) and its biologically active N-alkylphenothiazine compounds of composition L[RuCl3(eta(6)-p-cymene)] where L = CPH+ (2), TFH+center dot HCl (3), and TRH+ (4) (chlorpromazine hydrochloride, CP center dot HCl; trifluoperazine dihydrochloride, TF center dot 2HCl; and thioridazine hydrochloride, TR center dot HCl, respectively) has been studied. The crystal and molecular structure of compound 3 was determined earlier by single crystal X-ray diffraction analysis. The thermal data were collected by simultaneous TG/DSC measurements. For evolved gas detection, the qualitative reaction of chlorides with AgNO3 in an acidic solution was applied. The measurements were carried out in the temperature range to 700 A degrees C in nitrogen atmosphere. Compounds of L[RuCl3(eta(6)-p-cymene)] crystallize with water or water/2-propanole. On the basis of thermal data, the trend in the solvent bonding energies was assessed.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines", volume = "111", number = "3", pages = "1927-1932", doi = "10.1007/s10973-011-1969-8" }
Hollo, B., Krstić, M., Sovilj, S. P.,& Meszaros-Szecsenyi, K.. (2013). Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines. in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 111(3), 1927-1932. https://doi.org/10.1007/s10973-011-1969-8
Hollo B, Krstić M, Sovilj SP, Meszaros-Szecsenyi K. Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines. in Journal of Thermal Analysis and Calorimetry. 2013;111(3):1927-1932. doi:10.1007/s10973-011-1969-8 .
Hollo, Berta, Krstić, Milena, Sovilj, Sofija P., Meszaros-Szecsenyi, Katalin, "Thermal decomposition of new chlorido(p-cymene) ruthenium(II) complexes containing N-alkylphenothiazines" in Journal of Thermal Analysis and Calorimetry, 111, no. 3 (2013):1927-1932, https://doi.org/10.1007/s10973-011-1969-8 . .